To answer your question about the one way valve, yes there is a plastic one way valve in the hot water discharge port (top of the hot water heater). Turning the bottom valve to "operate" will direct water into the HWH where it is heated and supplied to the RV plumbing. Turning that same valve to "winterize" will direct the water away from the HWH and will bypass the HWH making winterizing easier and will use much less antifreeze.
There are some dealers who do a great job of explaining the RV details during the PDI, some dealers who do a lousy job and there are some customers who are so "overwhelmed" that they simply don't remember everything that is was covered.
Fortunately, the owner's manual supplied by Keystone covers much of the information you'll need. The hot water heater bypass valve is covered on page 55 of the current edition. Right after the "big red DANGER" symbol you'll find the comment about making sure the bypass valve is in the ON position and the water heater is full before turning on the gas or electric supply to avoid damage to the heater.
There's a load of good information in that manual. If you don't have a copy, you can download one or read it online at this link:
http://www.keystonerv.com/customer-s.../owners-manual