If you have the "Montana" and the Legacy package, you have dual batteries because you also have a residential refrigerator. You also have an inverter that draws it's power from the batteries, to power the refrigerator when not plugged into shore power.
There is a red cut off switch inside your front bay area, probably on the wall behind the battery area that kills power to the inverter. You also have the main battery cut off switch for the rest of the 12 volt DC items in the coach.... except the CO2 detector, which is never disabled, unless the batteries themselves are disconnected.
Many folks install a cut off switch on the negative battery cable, as there is only one cable connected to the negative side.
Congrats on your new Montana.
Why not jump over to the Montana Owners Culb forums (sponsored by the same organization that sponsors this site... RV Life.
Click Here. You can sign up with the same user ID and password you use here and enjoy using both forum sites. The Montana site is everything specific for Montana owners, this site is for anyone with a Keystone product. Between the 2 sites, you will ALWAYS find your answers.
Enjoy that Montana, you've got a nice one! Happy Camping.
Edit: As far as the dual purpose batteries, unfortunately not everyone understands the difference between a dual purpose and deep cycle battery. More than likely, the original batteries were replaced by the previous owner, or might have even been swapped out by your RV dealership (If you purchased from a dealer) because they either did not know the difference, couldn't find a deep cycle battery, simply did not want to pay the price for a deep cycle batteries, or maybe couldn't find deep cycle batteries the same size as the originals to fit the space where they sit.