Welcome to the forum
As a rule Filon is bought in a roll, and should be adhered to a sheet of backing prior to installation. In your case wanting to curve I would use the thinnest Luan you can get. We use a spray adhesive, I can give you the name when I go to work tomorrow.
Since either filon or sheet metal will only be secured at the edges, make sure you place the fasteners as close to the edge as possible so the corner molding covers them.
FWIW, I do RV collision work for a living now, so I may have an insight.
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2012 Copper Canyon 273FWRET being towed by a 1994 Ford F350 CC,LB,Dually diesel.
Airlift 5000 bags, Prodigy brake control, 5 gauges on the pillar.Used to tow a '97 Jayco 323RKS.
Now an RVIA registered tech. Retired from Law enforcement in 2008 after 25+ yrs.